📅 30 October 2025
DOI: 10.31942/inteka.v10i4.14706
SYNERGISTIC INTERFACIAL CHEMISTRY OF HUMIC ACID AND ACTIVATED FLY ASH FOR HIGH-PERFORMANCE Mn²⁺ ADSORPTION
Jurnal Inovasi Teknik Kimia
Universitas Wahid Hasyim
📄 Abstract
This study developed a hybrid adsorbent derived from activated fly ash (FA) and humic acid (HA) for effective Mn²⁺ removal from aqueous solutions. Fly ash was activated using 1 M NaOH to increase its surface hydroxyl groups (≡Si–OH and ≡Al–OH) and enhance reactivity. The activated FA was then composited with HA, which contains abundant –COOH and –OH groups, forming an inorganic–organic hybrid with improved adsorption capability. The HA–FA composite with a 1:3 mass ratio exhibited the highest Mn²⁺ removal efficiency of 98.80% after 120 minutes, significantly outperforming both HA and FA individually. FTIR analysis confirmed the formation of Si–O–C and Al–O–C linkages, indicating strong chemical interactions between the mineral and organic phases. Statistical analysis (Shapiro–Wilk, Levene, and ANOVA; p < 0.05) demonstrated that both adsorbent composition and contact time significantly influenced the adsorption efficiency. Overall, the HA–FA hybrid represents a low-cost, sustainable, and high-performance adsorbent capable of efficiently removing heavy metals from wastewater, providing a promising approach for transforming industrial and natural wastes into functional environmental materials
🔖 Keywords
#Adsorption; Activated Fly Ash; Humic Acid; Manganese; Heavy metal removal
ℹ️ Informasi Publikasi
Tanggal Publikasi
30 October 2025
Volume / Nomor / Tahun
Volume 11, Nomor 1, Tahun 2025
📝 HOW TO CITE
Susparini, Ninik Triayu; Ramadhan, Alamsyah Sultan; Aferta, Lusi; Benu, Marlon Jusak Renaldy; Wijayanti, Sri; Tantowi, Ali, "SYNERGISTIC INTERFACIAL CHEMISTRY OF HUMIC ACID AND ACTIVATED FLY ASH FOR HIGH-PERFORMANCE Mn²⁺ ADSORPTION," Jurnal Inovasi Teknik Kimia, vol. 11, no. 1, Oct. 2025.
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